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triethylborane solution (c15-1294-731)

TRIETHYLBORANE 1.0M SOLUTION IN TETRAHYDROFURAN (C005B-092072)

Catalog No.
C005B-092072
Manufacturer No.
179701-100ML
Manufacturer Name
Sigma-Aldrich
Quantity
100
Unit of Measure
ML

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Application Catalyst for: Allylation of aldehydes Decarboxylative C-C bond cleavage reactions Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations Regioselective hydroxyalkylation of unsaturated oxime ethers Reactant for radical

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Application

Catalyst for:

  • Allylation of aldehydes
  • Decarboxylative C-C bond cleavage reactions
  • Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations
  • Regioselective hydroxyalkylation of unsaturated oxime ethers

Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes

Reactant for synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential

Triethylborane is used as a catalyst for:

  • Allylation of aldehydes
  • Decarboxylative C-C bond cleavage reactions
  • Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations
  • Regioselective hydroxyalkylation of unsaturated oxime ethers


It can be employed as a reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes and for the synthesis of tetramethylammonium trialkylphenylborate salts.

Molecular Weight: 97.99. Empirical Formula: C6H15B. linearFormula: (C2H5)3B. form: liquid. Quality Level: 100. reaction suitability: reagent type: reductant. concentration: 1.0 . M in THF. density: 0.865 . g/mL . at 25 . °C. SMILES string: CCB(CC)CC. InChI: 1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3. InChI key: LALRXNPLTWZJIJ-UHFFFAOYSA-N. Pictograms: GHS02,GHS05,GHS07,GHS08. Signal Word: Danger. Hazard Statements: H225 - H250 - H261 - H302 - H314 - H335 - H336 - H351. Precautionary Statements: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378. Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1A - Water-react 2. Supp Hazards: EUH019. Storage Class Code: 4.2 - Pyrophoric and self-heating hazardous materials. WGK: WGK 1. Flash Point(F): 1.4 °F - closed cup. Flash Point(C): -17 °C - closed cup. Personal Protective Equipment: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter.
UPC:
12191504
Condition:
New
HazmatClass:
Yes
MPN:
179701-100ML
CAS:
97-94-9
Temperature Control Device:
Yes

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