TRIETHYLBORANE 1.0M SOLUTION IN HEXANES (C005B-092075)

Application

Catalyst for:

• Allylation of aldehydes
• Decarboxylative C-C bond cleavage reactions
• Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations
• Regioselective hydroxyalkylation of unsaturated oxime ethers

Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes

Reactant for synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential

Triethylborane can be used:

• As a radical initiator and terminator of free-radical reactions in aqueous media.(1)
• To synthesize polymers such as poly(2-substituted-1-propenylene)s by reacting with 2-substituted allylic arsonium ylides.(2)

Molecular Weight: 97.99. Empirical Formula: C₆H₁₅B. linearFormula: (C₂H₅)₃B. form: liquid. Quality Level: 100. reaction suitability: reagent type: reductant. concentration: 1.0 . M in hexanes. density: 0.675 . g/mL . at 25 . °C. SMILES string: CCB(CC)CC. InChI: 1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3. InChI key: LALRXNPLTWZJIJ-UHFFFAOYSA-N. Pictograms: GHS02,GHS05,GHS07,GHS08,GHS09. Signal Word: Danger. Hazard Statements: H225 - H304 - H314 - H336 - H361f - H373 - H411. Precautionary Statements: P210 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338. Hazard Classifications: Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 3. Target Organs: Nervous system, Respiratory system. Storage Class Code: 4.3 - Hazardous materials, which set free flammable gases upon contact with water. WGK: WGK 2. Flash Point(F): -32.8 °F. Flash Point(C): -36 °C.