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cyclohexylzinc bromide solution

CYCLOHEXYLZINC BROMIDE 0.5M SOLUTION IN TETRAHYDROFURAN

Catalog No.
C005B-077298
Manufacturer No.
498033-50ML
Manufacturer Name
Sigma-Aldrich
Quantity
50
Unit of Measure
ML

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Application Cyclohexylzinc bromide is an organozinc reagent, generally used in Negishi coupling. Examples include the cross-coupling of alkylzinc halides with aryl/heteroaryl halides using Pd-PEPPSI-IPent and nickel-catalyzed synthesis of

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Application

Cyclohexylzinc bromide is an organozinc reagent, generally used in Negishi coupling. Examples include the cross-coupling of alkylzinc halides with aryl/heteroaryl halides using Pd-PEPPSI-IPent and nickel-catalyzed synthesis of 4-substituted coumarins.

It can react with the SO2 surrogate, 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct (DABSO) to afford zinc sulfinate salts which can be alkylated to synthesize various useful sulfones.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Molecular Weight: 228.45. Empirical Formula: C6H11BrZn. linearFormula: C6H11ZnBr. Quality Level: 100. concentration: 0.5 . M in THF. density: 0.963 . g/mL . at 25 . °C. storage temp.: 2-8°C. SMILES string: Br[Zn]C1CCCCC1. InChI: 1S/C6H11.BrH.Zn/c1-2-4-6-5-3-1. . /h1H,2-6H2. 1H. /q. . +1/p-1. InChI key: XHGMTEIVIUFIPO-UHFFFAOYSA-M. Pictograms: GHS02,GHS05,GHS07,GHS08. Signal Word: Danger. Hazard Statements: H225 - H302 - H314 - H335 - H336 - H351. Precautionary Statements: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338. Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B. Supp Hazards: EUH014 - EUH019. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Flash Point(F): 3.0 °F - closed cup. Flash Point(C): -16.1 °C - closed cup.
UPC:
51142501
Condition:
New
HazmatClass:
Yes
MPN:
498033-50ML
CAS:
7565-57-3
Temperature Control Device:
Yes

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