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phenethylzinc bromide solution

PHENETHYLZINC BROMIDE 0.5M SOLUTION IN TETRAHYDROFURAN

Catalog No.
C005B-031246
Manufacturer No.
499307-50ML
Manufacturer Name
Sigma-Aldrich
Quantity
50
Unit of Measure
ML

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Application Phenethylzinc bromide can be used as a reagent: In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation.

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Application

Phenethylzinc bromide can be used as a reagent:

  • In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation.
  • To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction.
  • To synthesize benzyl substituted thienopyrimidine derivatives.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Molecular Weight: 250.45. Empirical Formula: C8H9BrZn. linearFormula: C6H5CH2CH2ZnBr. Quality Level: 100. concentration: 0.5 . M in THF. bp: 65 . °C. density: 0.965 . g/mL . at 25 . °C. storage temp.: 2-8°C. SMILES string: Br[Zn]CCc1ccccc1. InChI: 1S/C8H9.BrH.Zn/c1-2-8-6-4-3-5-7-8. . /h3-7H,1-2H2. 1H. /q. . +1/p-1. InChI key: SEXSOTWHLBYVNF-UHFFFAOYSA-M. Pictograms: GHS02,GHS07,GHS08. Signal Word: Danger. Hazard Statements: H225 - H319 - H335 - H336 - H351. Precautionary Statements: P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313. Hazard Classifications: Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2. Supp Hazards: EUH014 - EUH019. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Flash Point(F): 1.4 °F - closed cup. Flash Point(C): -17 °C - closed cup.
UPC:
12191504
Condition:
New
HazmatClass:
Yes
MPN:
499307-50ML
CAS:
308796-14-7
Temperature Control Device:
Yes

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