ISOBUTYLZINC BROMIDE 0.5M SOLUTION IN TETRAHYDROFURAN

Application

Isobutylzinc bromide is an organozinc compound, which can be used as a reagent in the palladium-catalyzed Negishi cross-coupling reaction to construct a carbon-carbon bond by reacting with aryl or heteroaryl halides . It is also used to prepare regioselective unsaturated ketones by reacting with tert-butyl isocyanide via an allylic carbonylative coupling reaction in the presence of a nickel catalyst.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Molecular Weight: 202.41. Empirical Formula: C₄H₉BrZn. linearFormula: (CH₃)₂CHCH₂ZnBr. Quality Level: 100. concentration: 0.5 . M in THF. density: 0.943 . g/mL . at 25 . °C. storage temp.: 2-8°C. SMILES string: CC(C)C[Zn]Br. InChI: 1S/C4H9.BrH.Zn/c1-4(2)3. . /h4H,1H2,2-3H3. 1H. /q. . +1/p-1. InChI key: WYBHVVXVUCUWSE-UHFFFAOYSA-M. Pictograms: GHS02,GHS07,GHS08. Signal Word: Danger. Hazard Statements: H225 - H261 - H302 - H315 - H319 - H335 - H351. Precautionary Statements: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235. Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react 2. Target Organs: Respiratory system. Supp Hazards: EUH019. Storage Class Code: 4.3 - Hazardous materials, which set free flammable gases upon contact with water. WGK: WGK 3. Flash Point(F): 1.4 °F - closed cup. Flash Point(C): -17.0 °C - closed cup.