(TRIMETHYLSILYLMETHYL)MAGNESIUM CHLORIDE 1.0M SOLUTION IN DIETHYL ETHER

Application

Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides.

Molecular Weight: 146.97. Empirical Formula: C₄H₁₁ClMgSi. linearFormula: (CH₃)₃SiCH₂MgCl. Quality Level: 100. reaction suitability: reaction type: Grignard Reaction. concentration: 1.0 . M in diethyl ether. density: 0.777 . g/mL . at 25 . °C. SMILES string: C[Si](C)(C)C[Mg]Cl. InChI: 1S/C4H11Si.ClH.Mg/c1-5(2,3)4. . /h1H2,2-4H3. 1H. /q. . +1/p-1. InChI key: NAQATMJWCJCHOZ-UHFFFAOYSA-M. Pictograms: GHS02,GHS05,GHS07. Signal Word: Danger. Hazard Statements: H225 - H302 - H314 - H336. Precautionary Statements: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338. Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3. Target Organs: Central nervous system. Supp Hazards: EUH014 - EUH019. Storage Class Code: 4.3 - Hazardous materials, which set free flammable gases upon contact with water. WGK: WGK 3. Flash Point(F): -40.0 °F - closed cup. Flash Point(C): -40 °C - closed cup. Personal Protective Equipment: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter.