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BENZYLMAGNESIUM CHLORIDE 1.0M SOLUTION IN DIETHYL ETHER (C005B-057537)

Catalog No.
C005B-057537
Manufacturer No.
302759-800ML
Manufacturer Name
Sigma-Aldrich
Quantity
800
Unit of Measure
ML

Benzylmagnesium chloride is a versatile Grignard reagent frequently used in organic synthesis. It can be used as a reagent in the addition reaction with carbonyl compounds, nitriles, epoxides, and alkyl halides to synthesize various alcohols,

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General description

Benzylmagnesium chloride is a versatile Grignard reagent frequently used in organic synthesis. It can be used as a reagent in the addition reaction with carbonyl compounds, nitriles, epoxides, and alkyl halides to synthesize various alcohols, amines, and ketones. Additionally, it is also used in reductions, cross-coupling, allylation and alkylation reactions.

Application

Benzylmagnesium chloride solution (1.0 M in diethyl ether) is used as a reagent to provide the benzyl group required for the synthesis of the desired sulfonic acid-functionalized alkoxysilane. It is also used in the anionic polymerization of styrene to form styrenyl magnesium chloride, which is further used as an initiator in the synthesis of polyolefin-block-polystyrene block copolymers.

Molecular Weight: 150.89. Empirical Formula: C7H7ClMg. linearFormula: C6H5CH2MgCl. Quality Level: 100. reaction suitability: reaction type: Grignard Reaction. concentration: 1.0 . M in diethyl ether. density: 0.794 . g/mL . at 25 . °C. SMILES string: Cl[Mg]Cc1ccccc1. InChI: 1S/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7. . /h2-6H,1H2. 1H. /q. . +1/p-1. InChI key: NRAFPLGJPPJUNB-UHFFFAOYSA-M. Pictograms: GHS02,GHS05,GHS07. Signal Word: Danger. Hazard Statements: H225 - H302 - H314 - H336. Precautionary Statements: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338. Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3. Target Organs: Central nervous system. Supp Hazards: EUH019. Storage Class Code: 3 - Flammable liquids. WGK: WGK 2. Flash Point(F): -40.0 °F - closed cup. Flash Point(C): -40 °C - closed cup. Personal Protective Equipment: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter.
UPC:
12141901
Condition:
New
HazmatClass:
Yes
MPN:
302759-800ML
CAS:
6921-34-2
Temperature Control Device:
Yes

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