TRIMETHYLPHOSPHINE 1.0M SOLUTION IN TETRAHYDROFURAN (C005B-050890)

General description

Trimethylphosphine is the reagent used in Mitsunobu reaction. It participates in the transformation of azides into carbamates, aziridines from azidoalcohols, iminophosphoranes and aza-Wittig reaction. Electron diffraction study of trimethylphosphine has been reported.

Application

Trimethylphosphine (PMe₃) solution is the suitable reagent used in the synthesis of Fe/Te cluster type complex, Fe₆Te₈(PMe₃)₆. It may be employed as a probe to investigate the acid sites in Y-zeolite. It may be used for the synthesis of hexakis(trimethylphosphine)tris-μ-methylene-diruthenium(III).

Molecular Weight: 76.08. Empirical Formula: C₃H₉P. linearFormula: (CH₃)₃P. form: liquid. Quality Level: 100. reaction suitability: reagent type: ligand
reaction type: Mitsunobu Reaction, reagent type: ligand
reaction type: Wittig Reaction. concentration: 1.0 . M in THF. density: 0.872 . g/mL . at 25 . °C. functional group: phosphine. SMILES string: CP(C)C. InChI: 1S/C3H9P/c1-4(2)3/h1-3H3. InChI key: YWWDBCBWQNCYNR-UHFFFAOYSA-N. Pictograms: GHS02,GHS07,GHS08. Signal Word: Danger. Hazard Statements: H225 - H302 - H315 - H319 - H335 - H351. Precautionary Statements: P201 - P210 - P233 - P261 - P280 - P304 + P340 + P312. Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3. Target Organs: Respiratory system. Supp Hazards: EUH018 - EUH019. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Flash Point(F): -22.0 °F - closed cup. Flash Point(C): -30 °C - closed cup. Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter.