(R)-(-)-CARVONE 98% (98% EE/GLC) (C005B-055379)

General description

(R)-(−)-Carvone is a monoterpenoid. Its ozonolysis in the gaseous phase has been proposed. Aldehydes (formaldehyde) and biradicals were obtained as the major products. It participates in the diastereoselective synthesis of homochiral octalones.

Application

(R)-(−)-Carvone may be employed as starting reagent for the synthesis of enantiopure (R)-(+)-3-methyl-6-isopropenyl-cyclohept-3-enone-1, a useful intermediate formed during the synthesis of terpenoids. It may be employed as starting reagent for the synthesis of differently protected (4S,6R,7R)-trihydroxy-1-octyne derivatives.

Chiral starting material.

Molecular Weight: 150.22. Empirical Formula: C₁₀H₁₄O. vapor density: 5.2 (vs air). Quality Level: 100. vapor pressure: 0.4 mmHg ( 20 °C). Assay: 98%. form: liquid. optical activity: [α. ]20/D −. 61°, neat. refractive index: n20/D 1.497 (lit.). bp: 227-230 . °C (lit.). density: 0.959 . g/mL . at 25 . °C (lit.). SMILES string: CC(: C)[C@@H]1CC: C(C)C(: O)C1. InChI: 1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m1/s1. InChI key: ULDHMXUKGWMISQ-SECBINFHSA-N. Pictograms: GHS07. Signal Word: Warning. Hazard Statements: H302 - H317. Precautionary Statements: P261 - P264 - P272 - P280 - P301 + P312 - P302 + P352. Hazard Classifications: Acute Tox. 4 Oral - Skin Sens. 1. Storage Class Code: 10 - Combustible liquids. WGK: WGK 1. Flash Point(F): 192.2 °F - closed cup. Flash Point(C): 89 °C - closed cup. Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter.