MERCURY(II) BROMIDE ACS REAGENT (C005B-080211)

General description

Mercury(II) bromide (HgBr₂) affords 1:1 adducts on reaction with N,N,N′,N′- tetramethyl-o-phenylenediamine. Single-crystal X-ray diffraction studies of these adducts have been reported. It forms complexes by reacting with 3,12-dimethylbenzo[a]quinoxalino[2,3-c]phenazine ligand.

Application

Mercury(II) bromide (HgBr₂) may be used in the preparation of mononuclear [Hg(L1)Br₂] and 1D polymer [Hg₂(L2)Br₄]_n [L1 = (N,N-diethyl,N′-(pyridin-2-yl)formylidene)ethane-1,2-diamine and L2 = (N,N-diethyl,N′-(pyridin-2-yl)benzylidene)ethane-1,2-diamine]. It may also be used as a promoter in the glycoslyation reaction of alcohols.

Molecular Weight: 360.40. Empirical Formula: Br₂Hg. linearFormula: HgBr₂. grade: ACS reagent. Quality Level: 200. vapor pressure: 1 mmHg ( 136.5 °C). form: powder. reaction suitability: reagent type: catalyst
core: mercury. impurities: ≤. 0.05% insol. CH₃OH. reduction residue: ≤. 0.02%. color: white to very faintly yellow. bp: 322 . °C (lit.). mp: 236 . °C (lit.). anion traces: chloride (Cl^-): ≤. 0.25%. SMILES string: Br[Hg]Br. InChI: 1S/2BrH.Hg/h2*1H. /q. . +2/p-2. InChI key: NGYIMTKLQULBOO-UHFFFAOYSA-L. Pictograms: GHS06,GHS08,GHS09. Signal Word: Danger. Hazard Statements: H300 + H310 + H330 - H373 - H410. Precautionary Statements: P262 - P264 - P273 - P280 - P302 + P352 + P310 - P304 + P340 + P310. Hazard Classifications: Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2. Storage Class Code: 6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials. WGK: WGK 3. Flash Point(F): Not applicable. Flash Point(C): Not applicable.