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MERCURY(II) ACETATE ACS REAGENT >=; 98.0% (C005B-020576)

Catalog No.
C005B-020576
Manufacturer No.
176109-500G
Manufacturer Name
Sigma-Aldrich
Quantity
500
Unit of Measure
GR

Mercury(II) acetate forms various addition compounds with olefins. Polarographic evaluation of these addition compounds has been proposed.

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General description

Mercury(II) acetate forms various addition compounds with olefins. Polarographic evaluation of these addition compounds has been proposed. It participates in the synthesis of nitrate esters, acetate esters, alcohols and ethers.

Mercury(II) acetate is a reagent mainly used in oxymercuration-demercuration reaction.

Application

Due to its strong affinity towards sulfur, it finds application as a reagent in desulfurization reactions. Mercury(II) acetate may be used in the preparation of mercury(II) acetate-Nafion modified electrode, which can be used in anodic stripping voltammetry for the analysis of lead and copper ions in waste water samples.

Mercury(II) acetate may be used in the preparation of 2-benzylidene-3(2H)-benzofuran-3-ones (aurones). It may be used in the hydrothermal synthesis of [Hg2(apca)2]n [apca = 3-aminopyrazine-2-carboxylate], a new mercury(I)-organic framework based on Hg22 + dumbbell.

Molecular Weight: 318.68. Empirical Formula: C4H6HgO4. linearFormula: (CH3COO)2Hg. grade: ACS reagent. Quality Level: 200. Assay: ≥. 98.0%. form: powder. reaction suitability: reagent type: catalyst
core: mercury. impurities: ≤. 0.01% insolubles. reduction residue: ≤. 0.02%. mp: 179-182 . °C (lit.). anion traces: chloride (Cl-): ≤. 0.005%, nitrate (NO3-): ≤. 0.005%, sulfate (SO42-): ≤. 0.005%. cation traces: Fe: ≤. 0.001%, Hg+: ≤. 0.4%, other heavy metals (as Pb): ≤. 0.002%. SMILES string: CC(: O)O[Hg]OC(C): O. InChI: 1S/2C2H4O2.Hg/c2*1-2(3)4. /h2*1H3,(H,3,4). /q. . +2/p-2. InChI key: BRMYZIKAHFEUFJ-UHFFFAOYSA-L. Pictograms: GHS06,GHS08,GHS09. Signal Word: Danger. Hazard Statements: H300 + H310 + H330 - H373 - H410. Precautionary Statements: P262 - P264 - P273 - P280 - P302 + P352 + P310 - P304 + P340 + P310. Hazard Classifications: Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2. Storage Class Code: 6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials. WGK: WGK 3. Flash Point(F): Not applicable. Flash Point(C): Not applicable.
UPC:
12141726
Condition:
New
HazmatClass:
Yes
MPN:
176109-500G
CAS:
1600-27-7
Temperature Control Device:
Yes

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