General description
LiBr/Chlorotrimethylsilane reagent participates in the conversion of alcohols to bromides.
Application
Lithium bromide (LiBr) may be employed as a catalyst in the following studies:
- Transformation of (aromatic- and α,β-unsaturated) aldehydes to dithioacetals via solvent-free dithioacetalization.
- Synthesis of olefins via condensation reaction of carbonyl compounds with active methylene compounds.
- Green synthesis of β-amino alcohols.
- Chemo- and regioselective bromination of aromatic compounds was carried out by employing LiBr/ceric ammonium nitrate (CAN) reagent system (as a source of Br+ ion).
Other Notes
Go to Redi-Dri™ Product Listing 746479
Legal Information
ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC
Redi-Dri is a trademark of Sigma-Aldrich Co. LLC
Molecular Weight: 86.85. Empirical Formula: BrLi. linearFormula: LiBr. vapor pressure: 1 hPa ( 748 °C). Quality Level: 200. product line: ReagentPlus®. . Assay: ≥. 99%. form: powder. pH: 7 (20 . °C, 10 . g/L). mp: 550 . °C (lit.). SMILES string: [Li+].[Br-]. InChI: 1S/BrH.Li/h1H. /q. +1/p-1. InChI key: AMXOYNBUYSYVKV-UHFFFAOYSA-M. Pictograms: GHS07. Signal Word: Warning. Hazard Statements: H302 - H315 - H317 - H319. Precautionary Statements: P261 - P264 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338. Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1. Storage Class Code: 13 - Non Combustible Solids. WGK: WGK 1. Flash Point(F): Not applicable. Flash Point(C): Not applicable.- UPC:
- 12141705
- Condition:
- New
- HazmatClass:
- No
- MPN:
- 213225-2KG
- CAS:
- 7550-35-8
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