B-IODO-9-BBN 1.0M SOLUTION IN HEXANES

General description

B-Iodo-9-BBN is a boron-based organic compound that is commonly used as a reagent in organic synthesis for the iodoboration of alkynes, enolboration, the demethylation of phenol methyl ethers, and synthesis of boron-containing compounds.

Application

B-Iodo-9-BBN solution (1.0 M in hexanes) can be used as a Lewis acid in the selective synthesis of δ-keto esters via a Michael-type addition reaction to α,β-unsaturated ketones.

Molecular Weight: 247.91. Empirical Formula: C₈H₁₄BI. form: liquid. Quality Level: 100. concentration: 1.0 . M in hexanes. density: 0.816 . g/mL . at 25 . °C. SMILES string: IB1C2CCCC1CCC2. InChI: 1S/C8H14BI/c10-9-7-3-1-4-8(9)6-2-5-7/h7-8H,1-6H2/t7-,8+. InChI key: YAYIUFDUYUYPJC-OCAPTIKFSA-N. Pictograms: GHS02,GHS07,GHS08,GHS09. Signal Word: Danger. Hazard Statements: H225 - H304 - H315 - H336 - H361f - H373 - H411. Precautionary Statements: P201 - P210 - P273 - P301 + P310 + P331 - P302 + P352 - P308 + P313. Hazard Classifications: Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 Inhalation - STOT SE 3. Target Organs: Central nervous system, Nervous system. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Flash Point(F): -9.4 °F - closed cup. Flash Point(C): -23 °C - closed cup.