9-BBN 0.4M SOLUTION IN HEXANES (C005B-029185)

Application

Protecting group for alkenes†

Reactant for:

• Linear SPPS synthesis of ubiquitin derivatives
• Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides
• Intramolecular insertion of alkenes into palladium-nitrogen bonds
• Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast
• Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids

Molecular Weight: 122.02. Empirical Formula: C₈H₁₅B. Quality Level: 100. reaction suitability: reagent type: reductant. concentration: 0.4 . M in hexanes. bp: 68-70 . °C. density: 0.691 . g/mL . at 25 . °C. SMILES string: B1C2CCCC1CCC2. InChI: 1S/C8H15B/c1-3-7-5-2-6-8(4-1)9-7/h7-9H,1-6H2/t7-,8+. InChI key: FEJUGLKDZJDVFY-OCAPTIKFSA-N. Pictograms: GHS02,GHS07,GHS08,GHS09. Signal Word: Danger. Hazard Statements: H260 - H304 - H315 - H336 - H361f - H373 - H411. Precautionary Statements: P201 - P231 + P232 - P273 - P301 + P310 + P331 - P302 + P352 - P308 + P313. Hazard Classifications: Aquatic Chronic 2 - Asp. Tox. 1 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 Inhalation - STOT SE 3 - Water-react 1. Target Organs: Central nervous system, Nervous system. Storage Class Code: 4.3 - Hazardous materials, which set free flammable gases upon contact with water. WGK: WGK 3. Flash Point(F): Not applicable. Flash Point(C): Not applicable. Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter.