3-CHLOROPHENYLMAGNESIUM BROMIDE 0.5M SOLUTION IN TETRAHYDROFURAN

Application

3-Chlorophenylmagnesium bromide (o-chlorophnylmagnesium bromide) is a Grignard reagent that can be used to synthesize:

• 2,3-Di(o-chlorophenyl)buta-1,3-dienes by reacting with 1,4-dimethoxy 2-butyne in the presence of a copper(I) salt.
• 2-Bromo-5-chlorothiophen-3-yl-(3-chlorophenyl)methanol by reacting with 2-bromo-5-chlorothiophene-3-carbaldehyde.
• 2-(3-Chlorophenyl)-1-phenyl-1H-inden-1-ol from 2- benzoylbenzonitrile as a starting a material.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Molecular Weight: 215.76. Empirical Formula: C₆H₄BrClMg. reaction suitability: reaction type: Grignard Reaction. Quality Level: 100. concentration: 0.5 . M in THF. bp: 65 . °C (lit.). density: 0.960 . g/mL . at 25 . °C (lit.). storage temp.: 2-8°C. SMILES string: Clc1cccc([Mg]Br)c1. InChI: 1S/C6H4Cl.BrH.Mg/c7-6-4-2-1-3-5-6. . /h1-2,4-5H. 1H. /q. . +1/p-1. InChI key: ZIYRUWPTUPFRQU-UHFFFAOYSA-M. Pictograms: GHS02,GHS07,GHS08. Signal Word: Danger. Hazard Statements: H225 - H302 - H319 - H335 - H351. Precautionary Statements: P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235. Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3. Target Organs: Respiratory system. Supp Hazards: EUH019. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Flash Point(F): 1.4 °F - closed cup. Flash Point(C): < -17 °C - closed cup.