2-THIENYLMAGNESIUM BROMIDE SOLUTION 1.0M IN TETRAHYDROFURAN

Application

2-Thienylmagnesium bromide is a Grignard reagent that can be used as a reactant to synthesize:

• 1-(2-thienyl)-carbinols by condensation reaction with aldehydes. Carbinols are further dehydrated to form 2-thienyl olefins.
• Thiophene-functionalized polystyrene macromonomer (ThPStM), which is employed as a key intermediate to synthesize polystyrene-graft-polythiophene (PSt-g-PTh) via a combination of atom transfer radical polymerization (ATRP) and Grignard reaction.
• Thienylene oligomers, which are used as conducting polymers and as potential OLEDs.

Molecular Weight: 187.34. Empirical Formula: C₄H₃BrMgS. reaction suitability: reaction type: Grignard Reaction. Quality Level: 100. concentration: 1.0 . M in THF. bp: 65 . °C. density: 1.011 . g/mL . at 25 . °C. SMILES string: Br[Mg]c1cccs1. InChI: 1S/C4H3S.BrH.Mg/c1-2-4-5-3-1. . /h1-3H. 1H. /q. . +1/p-1. InChI key: GSHPYJFNTAMRJF-UHFFFAOYSA-M. Pictograms: GHS02,GHS07,GHS08. Signal Word: Danger. Hazard Statements: H225 - H302 - H319 - H335 - H351. Precautionary Statements: P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235. Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3. Target Organs: Respiratory system. Supp Hazards: EUH019. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Flash Point(F): -6.0 °F - closed cup. Flash Point(C): -21.1 °C - closed cup.