YU-WASA AUXILIARY 97%

Other Notes

Acidic amides are superior directing groups for promoting C-H activation reactions with both Pd(0)/PR₃ and Pd(II) catalysts.

Used in the Preparation of

• Lactams via palladium-catalyzed olefination of arylamides with benzylacrylate, followed by 1,4-conjugate addition
• N-(fluorinated aryl)benzamides as substrates for regioselective C-H amination reactions with O-benzoylhydroxylamines
• Substituted succinimides via palladium-catalyzed carbonylation of N-aryl amides
• N-aryl cyclopropanecarboxamide substrates and various amino acid ligands for palladium-catalyzed C-H activation of cyclopropanes

Molecular Weight: 233.09. Empirical Formula: C₇H₂F₇N. linearFormula: CF₃C₆F₄NH₂. Quality Level: 100. Assay: 97%. form: liquid. reaction suitability: reaction type: C-C Bond Formation, reagent type: catalyst
reaction type: C-H Activation. refractive index: n20/D 1.431 (lit.), n20/D 1.432. bp: 186 . °C (lit.). density: 1.662 . g/mL . at 25 . °C, 1.687 . g/mL . at 25 . °C (lit.). SMILES string: Nc1c(F)c(F)c(c(F)c1F)C(F)(F)F. InChI: 1S/C7H2F7N/c8-2-1(7(12,13)14)3(9)5(11)6(15)4(2)10/h15H2. InChI key: FJOACTZFMHZHSC-UHFFFAOYSA-N. Pictograms: GHS07. Signal Word: Warning. Hazard Statements: H315 - H319 - H335. Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338. Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3. Target Organs: Respiratory system. Storage Class Code: 10 - Combustible liquids. WGK: WGK 3. Flash Point(F): Not applicable. Flash Point(C): Not applicable.