XTALFLUOR-E(R) (C005B-054491)

General description

XtalFluor-E^® is widely used in formylation, ring expansion, proto-functionalization, cyclodehydration, and dehydration.

Application

Convenient crystalline highly chemoselective deoxofluorination reagent with a broad substrate scope

Deoxofluorination reagent with a better safety profile, that doesn′t generate corrosive HF which makes it suitable for use in standard borosilicate vessels, and does not react violently with water

Reactant for:

• Preparation of fluorodisaccharides

Triisopropylsilanethiol was recently reported by MacMillian and coworkers to be used as an organocatalyst, in tandem with Ir(III) specifically Aldrich product 688096, in photoredox catalysis. This approach directly couples a cyano-containing arene with an allylic sp³ C-H bond.

Other Notes

The direct arylation of allylic sp³ C–H bonds via organic and photoredox catalysis

Legal Information

XtalFluor-E is a registered trademark of OmegaChem, Inc.

Molecular Weight: 229.00. Empirical Formula: C₄H₁₀BF₆NS. form: solid. Quality Level: 100. mp: 84-87 . °C. storage temp.: −. 20°C. SMILES string: F[B-](F)(F)F.CC\[N+](CC): S(\F)F. InChI: 1S/C4H10F2NS.BF4/c1-3-7(4-2)8(5)6. 2-1(3,4)5/h3-4H2,1-2H3. /q+1. -1. InChI key: YLNKFQWRRIXZPJ-UHFFFAOYSA-N. Pictograms: GHS05,GHS06. Signal Word: Danger. Hazard Statements: H301 + H311 + H331 - H314. Precautionary Statements: P260 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338. Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B. Supp Hazards: EUH014. Storage Class Code: 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects. WGK: WGK 3. Flash Point(F): Not applicable. Flash Point(C): Not applicable.