TRIS(TRIMETHYLSILYL)PHOSPHINE 95%

Application

Tris(trimethylsilyl)phosphine (P(TMS)₃) can be used as a precursor for the syntheses of:

• Indium phosphide (InP) and indium gallium phosphide (InGaP) nanocrystals, type III-V semiconductors.
• Chiral TMS-phospholane which can be further used to synthesize various bisphospholane ligands for asymmetric catalysis.

Molecular Weight: 250.54. Empirical Formula: C₉H₂₇PSi₃. linearFormula: [(CH₃)₃Si]₃P. Quality Level: 100. Assay: 95%. form: liquid. reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand. refractive index: n20/D 1.502 (lit.). bp: 243-244 . °C (lit.). density: 0.863 . g/mL . at 25 . °C (lit.). functional group: phosphine. storage temp.: 2-8°C. SMILES string: C[Si](C)(C)P([Si](C)(C)C)[Si](C)(C)C. InChI: 1S/C9H27PSi3/c1-11(2,3)10(12(4,5)6)13(7,8)9/h1-9H3. InChI key: OUMZKMRZMVDEOF-UHFFFAOYSA-N. Pictograms: GHS02,GHS07. Signal Word: Danger. Hazard Statements: H250 - H261 - H315 - H319 - H335. Precautionary Statements: P210 - P222 - P231 + P232 - P302 + P352 - P305 + P351 + P338 - P370 + P378. Hazard Classifications: Eye Irrit. 2 - Pyr. Liq. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 2. Target Organs: Respiratory system. Storage Class Code: 4.2 - Pyrophoric and self-heating hazardous materials. WGK: WGK 3. Flash Point(F): Not applicable. Flash Point(C): Not applicable. Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter.