Triisopropylsilane is a highly selective reducing agent which can be used to prepare anti-1,2-diols.The bulky isopropyl groups (vs. ethyl) allow for more selective reductions, e.g., beta-selective reduction of anomeric C-phenyl ketals, but do not diminish their activity (e.g. in the copper triflate catalyzed reductive etherification of trimethylsilyl ethers). Used in a highly diastereoelective preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbene complex.
Specifications and Purity: ≥98%
MDL Number: MFCD00009657
Molecular Formula: C9H22Si
Molecular Weight: 158.36
PubChem CID: 6327611
Isomeric SMILES: CC(C)[Si](C(C)C)C(C)C
Beilstein Registry Number: 1733718
Related Documents: https://aladdin-for-icloud-store.oss-cn-hangzhou.aliyuncs.com/aladdinsci/pdp/sds/1/T107280-SCI_e453c6f1e4911a66407d748018dc6e03.pdf
- UPC:
- 51111815
- Condition:
- New
- HazmatClass:
- Yes
- WeightUOM:
- LB
- MPN:
- T107280-5ml
- CAS:
- 6485-79-6
- Physical Hazards:
- Flammable Liquid
- Product Size:
- 5ml
- Hazard Statement Codes:
- H315:H226
- Precautionary Statement Codes:
- P501:P403+P235:P403+P233:P405:P370+P378:P362+P364:P305+P351+P338:P304+P340:P303+P361+P353:P302+P352:P280:P271:P264:P261:P243:P242:P241:P240:P233:P210
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