TRIETHYLALUMINUM 1.0M SOLUTION IN HEXAN ES (C005B-092067)

Application

Triethylaluminum solution can be used:

• As a reagent in Alumino-Mannich reaction, where it reacts with iminium ion substrates for which the corresponding Petasis borono-Mannich reaction is unsuccessful.
• In the synthesis of macrocyclic binuclear aluminum complexes with efficient activities toward ring-opening polymerization of ε-caprolactone.
• To promote Claisen rearrangement of allyl vinyl ether derivatives along with the transfer of ethyl group to aldehydic carbon.
• As a reagent for copper-catalyzed asymmetric conjugate addition of alkenyl- and alkylalanes to α,β-unsaturated lactams.
• As a precursor to synthesize diethylaluminium cyanide, which is used as hydrocyanating reagent.

Molecular Weight: 114.16. Empirical Formula: C₆H₁₅Al. linearFormula: Al(C₂H₅)₃. form: liquid. Quality Level: 100. concentration: 1.0 . M in hexanes. density: 0.692 . g/mL . at 25 . °C. SMILES string: CC[Al](CC)CC. InChI: 1S/3C2H5.Al/c3*1-2. /h3*1H2,2H3. . InChI key: VOITXYVAKOUIBA-UHFFFAOYSA-N. Pictograms: GHS02,GHS05,GHS07,GHS08,GHS09. Signal Word: Danger. Hazard Statements: H225 - H250 - H252 - H260 - H304 - H314 - H336 - H361f - H411. Precautionary Statements: P210 - P231 + P232 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P370 + P378. Hazard Classifications: Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Self-heat. 2 - Skin Corr. 1A - STOT SE 3 - Water-react 1. Target Organs: Respiratory system. Supp Hazards: EUH014. Storage Class Code: 4.2 - Pyrophoric and self-heating hazardous materials. WGK: WGK 3. Flash Point(F): -0.4 °F - closed cup. Flash Point(C): -18 °C - closed cup. Personal Protective Equipment: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter.