TITANIUM(IV) ISOPROPOXIDE 97% (C005B-048049)

General description

Titanium(IV) isopropoxide is a titanium-based coordination compound, commonly used in the asymmetric Sharpless epoxidation reaction of allylic alcohols. It is also used as a catalyst in Kulinkovich reaction for the synthesis of cyclopropanes.

Application

Commonly used as a precursor for the preparation of Titania (TiO₂)

Novel metal oxide/phosphonate hybrids were formed from titanium(IV) isopropoxide in a two-step sol-gel process. Starting material for barium-strontium-titanate thin films. Used to make porous titanosilicates, potential ion-exchange materials for cleanup of radioactive wastes. Applied in the formation of a heterosupermolecule consisting of a TiO₂ nanocrystallite-viologen electron acceptor complex whose light-induced electron transfer has been demonstrated.

Packaging

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Product of Dorf Ketal

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Molecular Weight: 284.22. Empirical Formula: C₁₂H₂₈O₄Ti. linearFormula: Ti[OCH(CH₃)₂]₄. Quality Level: 200. Assay: 97%. form: liquid. reaction suitability: core: titanium, reagent type: catalyst. refractive index: n20/D 1.464 (lit.). bp: 232 . °C (lit.). mp: 14-17 . °C (lit.). density: 0.96 . g/mL . at 20 . °C (lit.). SMILES string: CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C. InChI: 1S/4C3H7O.Ti/c4*1-3(2)4. /h4*3H,1-2H3. /q4*-1. +4. InChI key: VXUYXOFXAQZZMF-UHFFFAOYSA-N. Pictograms: GHS02,GHS07. Signal Word: Warning. Hazard Statements: H226 - H319 - H336. Precautionary Statements: P210 - P233 - P240 - P241 - P242 - P305 + P351 + P338. Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3. Target Organs: Central nervous system. Storage Class Code: 3 - Flammable liquids. WGK: WGK 1. Flash Point(F): 105.8 °F - Pensky-Martens closed cup. Flash Point(C): 41 °C - Pensky-Martens closed cup. Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter.