TITANIUM(IV) CHLORIDE 1.0M SOLUTION IN DICHLOROMETHANE (C005B-077096)

General description

Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone. Neutral solutions of TiCl₄ having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) are used to synthesize nanosized titanium dioxide.

Application

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.

Molecular Weight: 189.68. Empirical Formula: Cl₄Ti. linearFormula: TiCl₄. vapor pressure: 24.09 psi ( 55 °C), 6.93 psi ( 20 °C). Quality Level: 100. form: liquid. reaction suitability: reagent type: catalyst
core: titanium. concentration: 0.95-1.10 . M NaOH (titration), 1.0 . M in methylene chloride. density: 1.365 . g/mL . at 25 . °C. SMILES string: Cl[Ti](Cl)(Cl)Cl. InChI: 1S/4ClH.Ti/h4*1H. /q. . . . +4/p-4. InChI key: XJDNKRIXUMDJCW-UHFFFAOYSA-J. Pictograms: GHS05,GHS06,GHS08. Signal Word: Danger. Hazard Statements: H314 - H331 - H336 - H351. Precautionary Statements: P202 - P261 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338. Hazard Classifications: Acute Tox. 3 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3. Target Organs: Central nervous system. Supp Hazards: EUH014. Storage Class Code: 6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials. WGK: WGK 2. Flash Point(F): Not applicable. Flash Point(C): Not applicable.