General description
Thiophenol is an organosulfur compound used as an intermediate to produce polymers.
Application
Thiophenol can undergo:
- Asymmetric Michael addition to diisopropyl maleate in the presence of a catalytic amount of cinchonine to form (s)-(−)-diisopropyl phenylthiosuccinate, which can be further converted to (R)-(+)-3,4-epoxy-1-butanol.
- Regioselective and stereoselective 1,4-addition to alkenylidenecyclopropanes leading to endo- or cis-vinyl sulfide adducts, a key step in the synthesis of karahanaenone.
- Diastereoselective addition to (S)-N-(α,β-unsaturated carbonyl)-γ-[(trityloxy)methyl]-γ-butyrolactams to form the corresponding β-(phenylthio)carboxylates.
- UPC:
- 51111820
- Condition:
- New
- HazmatClass:
- Yes
- MPN:
- T32808-100G
- CAS:
- 108-98-5
- Temperature Control Device:
- Yes
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