TERT-BUTYL NITRITE 90% (C005B-047617)

General description

tert-Butyl nitrite (TBN) is an efficient NO source. TBN participates in photocatalyzed conversion of aryl- and heteroarylamines to selenides. It also participates in radical multifunctionalization reactions of aliphatic alkenes.

Application

tert-Butyl nitrite has been used as reagent:

• for diazotization and nitros­ation of alcohols, thiols, amines and cycloalkanes
• for the preparation of aryl azides from aryl amines

Other Notes

remainder 2-methyl-2-propanol

Molecular Weight: 103.12. Empirical Formula: C₄H₉NO₂. linearFormula: (CH₃)₃CONO. Quality Level: 200. Assay: 90%. refractive index: n20/D 1.368 (lit.). bp: 61-63 . °C (lit.). solubility: alcohol: very soluble(lit.), carbon disulfide: very soluble(lit.), chloroform: very soluble(lit.), diethyl ether: very soluble(lit.), glycerol: insoluble (practically)(lit.), water: slightly soluble(lit.). density: 0.867 . g/mL . at 25 . °C (lit.). storage temp.: 2-8°C. SMILES string: CC(C)(C)ON: O. InChI: 1S/C4H9NO2/c1-4(2,3)7-5-6/h1-3H3. InChI key: IOGXOCVLYRDXLW-UHFFFAOYSA-N. Pictograms: GHS02,GHS07. Signal Word: Danger. Hazard Statements: H225 - H302 + H332. Precautionary Statements: P210 - P233 - P240 - P241 - P301 + P312 - P304 + P340 + P312. Hazard Classifications: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2. Storage Class Code: 3 - Flammable liquids. WGK: WGK 1. Flash Point(F): 14.0 °F - closed cup. Flash Point(C): -10 °C - closed cup. Personal Protective Equipment: Eyeshields, Faceshields, Gloves.