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sulfuryl chloride (c15-1282-277)

SULFURYL CHLORIDE 97% (C005B-080378)

Catalog No.
C005B-080378
Manufacturer No.
157767-1L
Manufacturer Name
Sigma-Aldrich
Quantity
1
Unit of Measure
LI

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Sulfuryl chloride is a sulfur containing reagent. It is widely used for chlorination of various compounds, as it dissociates into sulfur dioxide and chlorine during reaction.

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General description

Sulfuryl chloride is a sulfur containing reagent. It is widely used for chlorination of various compounds, as it dissociates into sulfur dioxide and chlorine during reaction. Thus, it acts as a source of molecular chlorine for various aromatic chlorination reactions. Its chlorination reaction with dimethyl sulfide has been studied. Sulfuryl chloride may be used as an efficient reagent for the p-chlorination of phenols.

Application

Sulfuryl chloride (SO2Cl2) may be used in the following studies:

  • Synthesis of α-chloroketones.
  • Regioselective (ortho-selective) chlorination of phenols.
  • Conversion of monocyclic allylic cis-1,2-diols to the corresponding trans-1,2-chlorohydrins.
  • Preparation of β-chlorotetrahydrofuran derivatives.

Sulfuryl chloride may be used as an efficient reagent for the p-chlorination of phenols.

Molecular Weight: 134.97. Empirical Formula: Cl2O2S. linearFormula: SO2Cl2. vapor density: 4.7 (vs air). Quality Level: 200. vapor pressure: 100 mmHg ( 17.8 °C), 105 mmHg ( 20 °C). Assay: 97%. form: liquid. refractive index: n20/D 1.443 (lit.). bp: 68-70 . °C (lit.). mp: −. 54 . °C (lit.). density: 1.665 . g/mL . at 20 . °C (lit.). SMILES string: ClS(Cl)(: O): O. InChI: 1S/Cl2O2S/c1-5(2,3)4. InChI key: YBBRCQOCSYXUOC-UHFFFAOYSA-N. Pictograms: GHS05,GHS06. Signal Word: Danger. Hazard Statements: H314 - H330 - H335. Precautionary Statements: P260 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338. Hazard Classifications: Acute Tox. 2 Inhalation - Eye Dam. 1 - Skin Corr. 1C - STOT SE 3. Target Organs: Respiratory system. Supp Hazards: EUH014. Storage Class Code: 6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials. WGK: WGK 1. Personal Protective Equipment: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter.
UPC:
12352322
Condition:
New
HazmatClass:
Yes
MPN:
157767-1L
CAS:
7791-25-5

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