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sodium trimethylsilanolate (c15-1220-354)

SODIUM TRIMETHYLSILANOLATE 95% (C005B-022610)

Catalog No.
C005B-022610
Manufacturer No.
329576-25G
Manufacturer Name
Sigma-Aldrich
Quantity
25
Unit of Measure
GR

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Sodium trimethylsilanolate is a versatile and very powerful reagent for the conversion of esters to carboxylic acids and the hydrolysis of nitriles to primary amides. It can be used as a starting material for the synthesis of metal silanolates via

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General description

Sodium trimethylsilanolate is a versatile and very powerful reagent for the conversion of esters to carboxylic acids and the hydrolysis of nitriles to primary amides. It can be used as a starting material for the synthesis of metal silanolates via the salt metathesis and as a catalyst for the silylation of silanols with hydrosilanes.

Application

Sodium trimethylsilanolate is used as a catalyst in the:

  • Synthesis of the rhodium silonate complex.
  • Silylation of methylphenylsilane with tert-butyldimethylsilanol to synthesize trisiloxanes.

Molecular Weight: 112.18. Empirical Formula: C3H9NaOSi. linearFormula: (CH3)3SiONa. Quality Level: 100. Assay: 95%. mp: 230 . °C (dec.) (lit.). SMILES string: [Na+].C[Si](C)(C)[O-]. InChI: 1S/C3H9OSi.Na/c1-5(2,3)4. /h1-3H3. /q-1. +1. InChI key: HSNUIYJWTSJUMS-UHFFFAOYSA-N. Pictograms: GHS05. Signal Word: Danger. Hazard Statements: H314. Precautionary Statements: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363. Hazard Classifications: Skin Corr. 1B. Storage Class Code: 8A - Combustible, corrosive hazardous materials. WGK: WGK 3. Flash Point(F): 230.0 °F - closed cup. Flash Point(C): 110 °C - closed cup. Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges.
UPC:
51111907
Condition:
New
HazmatClass:
Yes
MPN:
329576-25G
CAS:
18027-10-6

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