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slap ta

SLAP TA

Catalog No.
C005B-024977
Manufacturer No.
900755-500MG
Manufacturer Name
Sigma-Aldrich
Quantity
500
Unit of Measure
MG

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Application When used with aliphatic or aromatic aldehydes, this silicon amine protocol SLAP reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy) 2

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Application

When used with aliphatic or aromatic aldehydes, this silicon amine protocol SLAP reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)2dtbbpy]PF6 (747769) is used with a recommended starting combination of Lewis acids Bi(OTf)3 (633305) and Cu(OTf)2 (283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents and is well-suited for scale-up reactions.

Other Notes

Molecular Weight: 177.38. Empirical Formula: C7H19NSSi. Quality Level: 100. Assay: 95%. form: liquid. density: 0.90452. storage temp.: 2-8°C. Pictograms: GHS02. Signal Word: Warning. Hazard Statements: H226. Precautionary Statements: P210 - P370 + P378. Hazard Classifications: Flam. Liq. 3. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Flash Point(F): 75.0 °F. Flash Point(C): 23.89 °C.
UPC:
42181506
Condition:
New
HazmatClass:
Yes
MPN:
900755-500MG
CAS:
2093935-86-3
Temperature Control Device:
Yes

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