(S)-(-)-BINAP (C007B-031359)

This product and its derivatives, rhodium and ruthenium are highly selective homogeneous catalysts used for the reduction of aryl ketones, β-keto esters, and α-amino ketones. They have also been used for asymmetric hydrogenation and hydroformylation of olefins, asymmetric Heck reactions, and asymmetric isomerizations of allyls. Ligand used in a palladium-catalyzed, asymmetric, tandem Heck reaction-carbanion capture process leading to a synthesis of a tricyclic sesquiterpene. Also used in a ruthenium-catalyzed asymmetric hydrogenation of α,β-unsaturated acids.Reactant involved in : Enantioselective and diastereoselective unpoled carbonyl allylation;Syntehsis of organophophine oxides as anittumor agents;SN2 halogenation of hydroxy groups;Synthesis of BINAP complexes and Studies of conformational flexibility of BINAP chelates.

Specifications and Purity: ≥98%

MDL Number: MFCD00010805

Molecular Formula: C44H32P2

Molecular Weight: 622.67

PubChem CID: 634876

Isomeric SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8

Beilstein Registry Number: 5321443

Related Documents: https://ald-pub-files.oss-cn-shanghai.aliyuncs.com/aladdinsci/pdp/sds/1/B109538-SCI_4a1fdf5b68c2676554b3d10033264e9d.pdf