Name: (R)-RU(OAC)2(BINAP) (C005B-032660)
SKU: C005B-032660
Availability: OutOfStock

(R)-RU(OAC)2(BINAP) (C005B-032660)

Catalog No.

C005B-032660

Manufacturer No.

692220-500MG

Manufacturer Name

Sigma-Aldrich

Quantity

500

Unit of Measure

Application Takasago Ligands and Complexes for Asymmetric Reactions ( R )-Ru(OAc) 2 (BINAP) may be used as a catalyst for the asymmetric hydrogenation of 1,1′-disubstituted olefins, such as 1-methyleneindan and 1-methylenetetralins. It can

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Description
Specifications

Application

Takasago Ligands and Complexes for Asymmetric Reactions

(R)-Ru(OAc)₂(BINAP) may be used as a catalyst for the asymmetric hydrogenation of 1,1′-disubstituted olefins, such as 1-methyleneindan and 1-methylenetetralins. It can also catalyze the hydrogenation of 2-(trifluoromethyl)acrylic acid to form optically active 2-(trifluoromethyl)propionic acid.

Catalyst for:

Asymmetric hydrogenation reactions

Legal Information

Sold in collaboration with Takasago for research purposes only.

Molecular Weight: 841.83. Empirical Formula: C₄₈H₃₈O₄P₂Ru. form: powder. Quality Level: 100. storage temp.: 2-8Â°C. SMILES string: CC(: O)O[Ru]OC(C): O.c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8. InChI: 1S/C44H32P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38. 2*1-2(3)4. /h1-32H. 2*1H3,(H,3,4). /q. . . +2/p-2. InChI key: NMLZYEWNUCRSRJ-UHFFFAOYSA-L. Storage Class Code: 11 - Combustible Solids. WGK: WGK 3. Flash Point(F): Not applicable. Flash Point(C): Not applicable.