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(r)-(+)-beta-citronellol

(R)-(+)-¢€“‚¬-CITRONELLOL 97%

Catalog No.
C005B-008695
Manufacturer No.
303461-1G
Manufacturer Name
Sigma-Aldrich
Quantity
1
Unit of Measure
GR

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Application ( R )-(+)-β-Citronellol can be used to prepare: ( R )-(+)-β-citronellyl acetate by treating with vinyl acetate via trans esterification reaction using immobilized Rhizomucor miehei lipase as biocatalyst. ( R )-(+)-citronellal

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Application

(R)-(+)-β-Citronellol can be used to prepare:

  • (R)-(+)-β-citronellyl acetate by treating with vinyl acetate via trans esterification reaction using immobilized Rhizomucor miehei lipase as biocatalyst.
  • (R)-(+)-citronellal and (R)-(+)-citronellic acid by the oxidation reaction.
  • Citronellol aziridine by treating with 2,2,2-trichloroethoxysulfonamide by intermolecular olefin aziridination.

It can also be used as a starting material for the synthesis of (+)-integerrinecic acid lactone.

(R)-(+)-β-Citronellol can undergo:

  • Oxidation to form (R)-(+)-citronellal, an antifungal agent and (R)-(+)-citronellic acid.
  • Intermolecular olefin aziridination with 2,2,2-trichloroethoxysulfonamide to form citronellol aziridine for ring-opening reactions.
  • Series of reactions to form α2δ-ligands for treating generalized anxiety disorder and insomnia.

Molecular Weight: 156.27. Empirical Formula: C10H20O. linearFormula: (CH3)2C: CHCH2CH2CH(CH3)CH2CH2OH. vapor pressure: ~0.02 mmHg ( 25 °C). Quality Level: 100. Assay: 95%. form: liquid. optical activity: [α. ]19/D +5.3°, neat. refractive index: n20/D 1.456 (lit.). bp: 112-113 . °C/12 . mmHg (lit.). density: 0.857 . g/mL . at 25 . °C (lit.). SMILES string: C[C@@H](CCO)CC\C: C(\C)C. InChI: 1S/C10H20O/c1-9(2)5-4-6-10(3)7-8-11/h5,10-11H,4,6-8H2,1-3H3/t10-/m1/s1. InChI key: QMVPMAAFGQKVCJ-SNVBAGLBSA-N. Pictograms: GHS07. Signal Word: Warning. Hazard Statements: H315 - H319 - H335. Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338. Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3. Target Organs: Respiratory system. Storage Class Code: 10 - Combustible liquids. WGK: WGK 3. Flash Point(F): 212.0 °F - closed cup. Flash Point(C): 100 °C - closed cup. Personal Protective Equipment: Eyeshields, Gloves, type ABEK (EN14387) respirator filter.
UPC:
51111703
Condition:
New
HazmatClass:
No
MPN:
303461-1G
CAS:
1117-61-9

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