(R)-(-)-ALPHA-PHELLANDRENE >=95.0% GC SUM OF ENANTIOMERS (C005B-039520)

General description

(R)-(-)-α-Phellandrene is a monoterpene derivative.

Application

(R)-(-)-α-Phellandrene undergoes [4+2] cycloaddition with 2-naphthyl acetylenecarboxylate to form a chiral diene, which can act as a ligand for the rhodium-catalyzed asymmetric addition reactions. It may be used to synthesize (1S,5R)-5-(1-methylethyl)-2-methylidene-3-cyclohexen-1-yl hydroperoxide, which on reduction forms trans-yabunikkeol.

Molecular Weight: 136.23. Empirical Formula: C₁₀H₁₆. Quality Level: 200. Assay: ≥. 95.0% (sum of enantiomers, GC). form: liquid. optical activity: [α. ]20/D −. 225±5°, c :  . 10% in diethyl ether. bp: 171-174 . °C (lit.). density: 0.844 . g/mL . at 20 . °C (lit.). storage temp.: 2-8°C. SMILES string: CC(C)[C@H]1CC: C(C)C: C1. InChI: 1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4-6,8,10H,7H2,1-3H3/t10-/m1/s1. InChI key: OGLDWXZKYODSOB-SNVBAGLBSA-N. Pictograms: GHS02,GHS07,GHS08,GHS09. Signal Word: Danger. Hazard Statements: H226 - H304 - H317 - H410. Precautionary Statements: P210 - P273 - P280 - P301 + P310 - P303 + P361 + P353 - P331. Hazard Classifications: Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Sens. 1B. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Flash Point(F): 113.0 °F - closed cup. Flash Point(C): 45 °C - closed cup. Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter.