PHENYLMAGNESIUM BROMIDE 1.0M SOLUTION IN TETRAHYDROFURAN (C005B-003494)

Application

Phenylmagnesium bromide (PhMgBr) solution is an organomagnesium reagent mainly used in Grignard reaction, which finds application as the key step in the synthesis of (S)-2(diphenylmethyl)pyrrolidine, a chiral solvating agent for the NMR analysis. PhMgBr can also undergo palladium-catalyzed Grignard coupling with alkyl chlorides to form the cross-coupled product in good yield.

Other Notes

Storage below 25°C may cause crystallization. Warm gently to redissolve solid.

Molecular Weight: 181.31. Empirical Formula: C₆H₅BrMg. linearFormula: C₆H₅MgBr. Quality Level: 200. reaction suitability: reaction type: Grignard Reaction. concentration: 1.0 . M in THF. density: 1.004 . g/mL . at 25 . °C. SMILES string: Br[Mg]c1ccccc1. InChI: 1S/C6H5.BrH.Mg/c1-2-4-6-5-3-1. . /h1-5H. 1H. /q. . +1/p-1. InChI key: ANRQGKOBLBYXFM-UHFFFAOYSA-M. Pictograms: GHS02,GHS05,GHS07,GHS08. Signal Word: Danger. Hazard Statements: H225 - H314 - H335 - H336 - H351. Precautionary Statements: P202 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338. Hazard Classifications: Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B. Supp Hazards: EUH014 - EUH019. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Flash Point(F): 1.4 °F - closed cup. Flash Point(C): -17 °C - closed cup. Personal Protective Equipment: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter.