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pentylmagnesium bromide solution (c15-1258-362)

PENTYLMAGNESIUM BROMIDE 2.0M SOLUTION IN DIETHYL ETHER (C005B-057605)

Catalog No.
C005B-057605
Manufacturer No.
290998-800ML
Manufacturer Name
Sigma-Aldrich
Quantity
800
Unit of Measure
ML

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Application Pentylmagnesium bromide solution is a Grignard reagent that can be used in the preparation of: Alkanes via Ni or Cu-catalyzed cross-coupling reaction with alkyl fluorides. Hydroxypiperidinones via the addition-cyclization-deprotection

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Application

Pentylmagnesium bromide solution is a Grignard reagent that can be used in the preparation of:

  • Alkanes via Ni or Cu-catalyzed cross-coupling reaction with alkyl fluorides.
  • Hydroxypiperidinones via the addition-cyclization-deprotection process of aldimines.

It can also be used as a reagent to synthesize a key intermediate by olefin alkylation in the total synthesis of alkaloid, (+)-hyperaspine , and surface alkylation of H-terminated Si (111), by Si-C bond formation.

Molecular Weight: 175.35. Empirical Formula: C5H11BrMg. linearFormula: C5H11MgBr. Quality Level: 100. reaction suitability: reaction type: Grignard Reaction. concentration: 2.0 . M in diethyl ether. density: 0.947 . g/mL . at 25 . °C. SMILES string: CCCCC[Mg]Br. InChI: 1S/C5H11.BrH.Mg/c1-3-5-4-2. . /h1,3-5H2,2H3. 1H. /q. . +1/p-1. InChI key: ZXWGTPYWPZGZPT-UHFFFAOYSA-M. Pictograms: GHS02,GHS05,GHS07. Signal Word: Danger. Hazard Statements: H225 - H260 - H302 - H314 - H336. Precautionary Statements: P210 - P231 + P232 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338. Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1. Target Organs: Central nervous system. Supp Hazards: EUH014 - EUH019. Storage Class Code: 4.3 - Hazardous materials, which set free flammable gases upon contact with water. WGK: WGK 3. Flash Point(F): -40.0 °F - closed cup. Flash Point(C): -40 °C - closed cup. Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter.
UPC:
12141915
Condition:
New
HazmatClass:
Yes
MPN:
290998-800ML
CAS:
693-25-4
Temperature Control Device:
Yes

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