General description
Cyanomethylenetributylphosphorane (CMBP)-mediated reaction of p-toluenesulfonamide with alcohols has been investigated.
Application
p-Toluenesulfonamide has been employed:
- as nucleophile during tetrabutylammonium fluoride (TBAF) catalyzed vinyl aziridine opening reaction
- as reagent during selective aziridination of olefins catalyzed by dirhodium (II) caprolactamate
Legal Information
ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC
Molecular Weight: 171.22. Empirical Formula: C7H9NO2S. linearFormula: CH3C6H4SO2NH2. Quality Level: 200. product line: ReagentPlus®. . Assay: ≥. 99%. form: solid. mp: 134-137 . °C (lit.). SMILES string: Cc1ccc(cc1)S(N)(: O): O. InChI: 1S/C7H9NO2S/c1-6-2-4-7(5-3-6)11(8,9)10/h2-5H,1H3,(H2,8,9,10). InChI key: LMYRWZFENFIFIT-UHFFFAOYSA-N. Gene Information: human ... CA1(759), CA2(760), CA5A(763), CA5B(11238). Storage Class Code: 11 - Combustible Solids. WGK: WGK 1. Flash Point(F): 395.6 °F - closed cup. Flash Point(C): 202 °C - closed cup. Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves.- UPC:
- 12141705
- Condition:
- New
- HazmatClass:
- No
- MPN:
- 236330-10G
- CAS:
- 70-55-3
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