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MOLYBDENUM(V) CHLORIDE 95% (C005B-004458)

Catalog No.
C005B-004458
Manufacturer No.
208353-25G
Manufacturer Name
Sigma-Aldrich
Quantity
25
Unit of Measure
GR

Molybdenum(V)chloride is a Lewis acid widely used as a catalyst and reagent in many organicreactions. It can be prepared by direct chlorination of molybdenum metal or byrefluxing thionyl chloride and MoO 3 .

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General description

Molybdenum(V)chloride is a Lewis acid widely used as a catalyst and reagent in many organicreactions. It can be prepared by direct chlorination of molybdenum metal or byrefluxing thionyl chloride and MoO3.

Application

Molybdenum(V) chloride can be used as an efficient catalyst for:

  • Condensation of nitrobenzene with alcohols and C-C coupling of alkenyllithium reagents.
  • Direct amidation of benzylic alcohols with sulfonamides and carbamates.
It can be used for the chlorination of alkyl halides, alkenes, and alkynes.

It can also be used as aprecursor to synthesize alumina/molybdenum nanocomposites and methylenemolybdenumreagents for chemoselective carbonyl alkenation.

Molecular Weight: 273.21. Empirical Formula: Cl5Mo. linearFormula: MoCl5. vapor pressure: 1.75 mmHg ( 25 °C), 131 mmHg ( 250 °C). Quality Level: 100. Assay: 95%. form: powder. reaction suitability: reagent type: catalyst
core: molybdenum. impurities: <. 0.5% insoluble matter. bp: 268 . °C (lit.). mp: 194 . °C (lit.). density: 2.928 . g/mL . at 25 . °C (lit.). application(s): battery manufacturing. SMILES string: Cl[Mo](Cl)(Cl)(Cl)Cl. InChI: 1S/5ClH.Mo/h5*1H. /q. . . . . +5/p-5. InChI key: GICWIDZXWJGTCI-UHFFFAOYSA-I. Pictograms: GHS05,GHS08. Signal Word: Danger. Hazard Statements: H314 - H351. Precautionary Statements: P201 - P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 + P310. Hazard Classifications: Carc. 2 - Eye Dam. 1 - Skin Corr. 1B. Storage Class Code: 8A - Combustible, corrosive hazardous materials. WGK: WGK 3. Flash Point(F): Not applicable. Flash Point(C): Not applicable.
UPC:
12141727
Condition:
New
HazmatClass:
Yes
MPN:
208353-25G
CAS:
10241-05-1

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