MANGANESE(II) CHLORIDE ANHYDROUS BEADS -10 MESH 99.999% (C005B-002207)

Application

A novel high-spin hexanuclear Mn(III) cluster, [NaMn₆(OMe)₁₂(dbm)₆]⁺, was synthesized via MnCl₂ oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state. Also used in the formation of an active Mn(0) species useful for radical cyclization reactions.

Legal Information

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

Molecular Weight: 125.84. Empirical Formula: Cl₂Mn. linearFormula: MnCl₂. product line: AnhydroBeads^™. . Quality Level: 100. Assay: 99.999% trace metals basis. impurities: ≤. 15.0 . ppm Trace Metal Analysis . particle size: −. 10 . mesh. mp: 652 . °C (lit.). density: 2.98 . g/mL . at 25 . °C (lit.). SMILES string: Cl[Mn]Cl. InChI: 1S/2ClH.Mn/h2*1H. /q. . +2/p-2. InChI key: GLFNIEUTAYBVOC-UHFFFAOYSA-L. Pictograms: GHS05,GHS06,GHS08. Signal Word: Danger. Hazard Statements: H301 - H318 - H373. Precautionary Statements: P260 - P264 - P280 - P301 + P310 - P305 + P351 + P338 - P314. Hazard Classifications: Acute Tox. 3 Oral - Eye Dam. 1 - STOT RE 2. Target Organs: Brain. Storage Class Code: 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects. WGK: WGK 2. Flash Point(F): Not applicable. Flash Point(C): Not applicable. Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Faceshields, Gloves.