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manganese(ii) chloride bis(lithium chloride) complex solution

MANGANESE(II) CHLORIDE BIS(LITHIUM CHLORIDE) COMPLEX 0.5 M IN TETRAHYDROFURAN

Catalog No.
C005B-049666
Manufacturer No.
718114-100ML
Manufacturer Name
Sigma-Aldrich
Quantity
100
Unit of Measure
ML

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Application Catalyst for homocoupling of Grignard reagents using atmospheric oxygen as an oxidant Reactant for: Transmetalation reactions Nickel-imidazolium carbene-catalyzed coupling reactions Reagent for the preparation of Rieke manganese

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Application

Catalyst for homocoupling of Grignard reagents using atmospheric oxygen as an oxidant

Reactant for:

  • Transmetalation reactions
  • Nickel-imidazolium carbene-catalyzed coupling reactions

Reagent for the preparation of Rieke manganese

Molecular Weight: 210.63. Empirical Formula: Cl4Li2Mn. linearFormula: Li2MnCl4. form: liquid. Quality Level: 100. reaction suitability: core: manganese, reagent type: catalyst. concentration: 0.5 . M in THF. density: 0.956 . g/mL . at 25 . °C. SMILES string: [Li+].[Li+].Cl[Mn--](Cl)(Cl)Cl. InChI: 1S/4ClH.2Li.Mn/h4*1H. . . /q. . . . 2*+1. +2/p-4. InChI key: VJOUQNFWQPCDPE-UHFFFAOYSA-J. Pictograms: GHS02,GHS07,GHS08. Signal Word: Danger. Hazard Statements: H225 - H302 - H315 - H319 - H335 - H351. Precautionary Statements: P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235. Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3. Target Organs: Respiratory system. Supp Hazards: EUH019. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Flash Point(F): 1.4 °F - closed cup. Flash Point(C): -17.0 °C - closed cup.
UPC:
12141724
Condition:
New
HazmatClass:
Yes
MPN:
718114-100ML
CAS:
57384-24-4

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