LITHIUM CHLORIDE ANHYDROUS FREE-FLOWING REDI-DRI(TM) REAGENTPLUS(R) 99% (C005B-076349)

General description

Redi-Dri^™ technology eliminates clumping and the need for complicated procedures to keep your salts free-flowing. Keeping your salts dry helps improve your results by giving accurate measurements and easier-to-handle salts and buffers. Rather than drying your salts in an oven or desiccator or breaking them apart manually, Redi-Dri^™ ensures that your salts will remain easy-to-use for months without worrying about anti-caking agents. Even after repeated openings you can be assured that your results are always accurate. Redi-Dri^™ saves you time, energy and money by keeping your salts usable for longer!

Application

Lithium chloride can be used as a catalyst in the solvent-free:

• Cyanosilylation of aldehydes and ketones with cyanotrialkylsilanes to give silylated cyanohydrins.
• Microwave-assisted Claisen-Schmidt condensation to prepare α, β-unsaturated ketones.

It can also be used as:

• An additive in the Pd-catalyzed Stille coupling of aryl iodides with arylstannanes to synthesize corresponding biphenyls.
• A catalyst for the chemo- and regioselective demethylation of aryl methyl ethers to corresponding phenol products.

Features and Benefits

• Increased efficiency – Eliminate time and effort of loosening hardened powders
• Safety – Avoid risks of using tools of force to break up clumps
• Economy – Faster preparation and solvation increase productivity and reduce costs
• Assured quality – Excellent, expert-tested quality with no anti-caking agents
• Flexible volumes – Available from research amounts to scale-up quantities

Legal Information

ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

Molecular Weight: 42.39. Empirical Formula: ClLi. linearFormula: LiCl. grade: anhydrous. Quality Level: 100. product line: ReagentPlus^®. , Redi-Dri^™. . Assay: 99%. form: powder or crystals. quality: free-flowing. pH: 6. mp: 605 . °C (lit.). SMILES string: [Li+].[Cl-]. InChI: 1S/ClH.Li/h1H. /q. +1/p-1. InChI key: KWGKDLIKAYFUFQ-UHFFFAOYSA-M. Pictograms: GHS07. Signal Word: Warning. Hazard Statements: H302 - H315 - H319. Precautionary Statements: P264 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P332 + P313. Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2. Storage Class Code: 13 - Non Combustible Solids. WGK: WGK 1. Flash Point(F): Not applicable. Flash Point(C): Not applicable.