General description
Lead(II) oxide exists in two forms: red, tetragonal PbO and yellow rhombic PbO. It is amphoteric in nature but basic character is more prominent. It reacts with water and carbon dioxide to form basic lead(II) carbonate. Industrial preparation of PbO is by oxidation of molten lead with O2 or thermal decomposition of lead(II) nitrate, carbonate or hydroxide.1
Lead(II) oxide is a crystalline solid, which can be prepared by decomposition of lead carbonate or by heating molten lead in the presence of air. It can be used in the synthesis of lead(II) ethanoate by reaction with ethanoic acid.
Molecular Weight: 223.20. Empirical Formula: OPb. linearFormula: PbO. vapor pressure: 10 mmHg ( 0 °C). Quality Level: 200. grade: puriss. p.a.. Assay: ≥. 99.0% (KT). form: powder. impurities: ≤. 0.001% total nitrogen (N). color: yellow. pH: 9.9 (20 . °C, 100 . g/L). mp: 886 . °C (lit.). anion traces: chloride (Cl
-): ≤. 20 . mg/kg. cation traces: Ca: ≤. 10 . mg/kg, Cd: ≤. 5 . mg/kg, Co: ≤. 5 . mg/kg, Cr: ≤. 5 . mg/kg, Cu: ≤. 5 . mg/kg, Fe: ≤. 10 . mg/kg, K: ≤. 50 . mg/kg, Mg: ≤. 5 . mg/kg, Mn: ≤. 5 . mg/kg, Na: ≤. 50 . mg/kg, Ni: ≤. 5 . mg/kg, Zn: ≤. 5 . mg/kg. SMILES string: O: [PbH2]. InChI: 1S/O.Pb. InChI key: YEXPOXQUZXUXJW-UHFFFAOYSA-N. Pictograms: GHS07,GHS08,GHS09. Signal Word: Danger. Hazard Statements: H302 + H332 - H351 - H360D - H362 - H372 - H410. Precautionary Statements: P260 - P263 - P273 - P301 + P312 - P304 + P340 + P312 - P308 + P313. Hazard Classifications: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Lact. - Repr. 1A - STOT RE 1. Storage Class Code: 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects. WGK: WGK 3. Flash Point(F): Not applicable. Flash Point(C): Not applicable.