JOSIPHOS SL-J009-1 PD G3 (C005B-021758)

General description

Josiphos SL-J009-1 Pd G3 (Josiphos SL-J009-1-G3-palladacycle) is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. G3 precatalysts are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.

Molecular Weight: 924.28. Empirical Formula: C₄₅H₆₅FeNO₃P₂PdS. form: solid. Quality Level: 100. feature: generation 3. reaction suitability: core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst. mp: 180-186 . °C. functional group: phosphine. SMILES string: NC1: C(C: CC: C1)C2: C([Pd]OS(C)(: O): O)C: CC: C2.C[C@@H](P(C(C)(C)C)C(C)(C)C)[C]3[C](P(C4CCCCC4)C5CCCCC5)[C][C][C]3.[C]6[C][C][C][C]6.[Fe]. InChI: 1S/C27H47P2.C12H10N.C5H5.CH4O3S.Fe.Pd/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23. 13-12-9-5-4-8-11(12)10-6-2-1-3-7-10. 1-2-4-5-3-1. 1-5(2,3)4. . /h14,19-23H,8-13,15-18H2,1-7H3. 1-6,8-9H,13H2. 1-5H. 1H3,(H,2,3,4). . /q. . . . . +1/p-1/t21-. . . . . /m1...../s1. InChI key: GJFJVCUFUWXFEB-RPDSBUJNSA-M. Storage Class Code: 11 - Combustible Solids. WGK: WGK 3. Flash Point(F): Not applicable. Flash Point(C): Not applicable.