IRON(III) CHLORIDE SOLUTION 0.2 M IN 2-METHYLTETRAHYDROFURAN (C005B-078859)

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. FeCl₃ is used in many biomass conversion processes because of its unique properties such as nontoxicity, low-cost, abundance, and high selectivity. Here, this product is 0.2 M in 2-methyltetrahydrofuran and thus aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks", and has been enhanced for catalytic efficiency. Click here for more information.

Application

Iron(III) chloride in greener solvent, 2-methyltetrahydrofuran (2-MeTHF) can be used:

• As a mild oxidant for phenolic coupling reaction.
• In dimerizing aryllithiumsand ketone enolates.
• As a mild Lewis acid catalyst to catalyzes ene reactions.
• In Nazarov cyclizations, Michael additions, and acetonation reactions.

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Molecular Weight: 162.20. Empirical Formula: Cl₃Fe. linearFormula: FeCl₃. form: solution. Quality Level: 100. reaction suitability: core: iron, reagent type: catalyst. greener alternative product characteristics: Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Catalysis
Learn more about the Principles of Green Chemistry.. concentration: 0.2 . M in 2-methyltetrahydrofuran. refractive index: n20/D 1.414. density: 0.868 . g/mL . at 25 . °C. greener alternative category: , Aligned. SMILES string: Cl[Fe](Cl)Cl. InChI: 1S/3ClH.Fe/h3*1H. /q. . . +3/p-3. InChI key: RBTARNINKXHZNM-UHFFFAOYSA-K. Pictograms: GHS02,GHS05,GHS07. Signal Word: Danger. Hazard Statements: H225 - H290 - H302 - H315 - H318. Precautionary Statements: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338. Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2. Supp Hazards: EUH019. Storage Class Code: 3 - Flammable liquids. WGK: WGK 2. Flash Point(F): 14.0 °F - closed cup. Flash Point(C): -10.0 °C - closed cup.