GRUBBS CATALYST(R) M204 CHEMBEADS (C005B-027199)

Application

Grubbs Catalyst^® M204 can be used as a catalyst for ring-closing metathesis (RCM), cross-metathesis, and ring-opening metathesis polymerization (ROMP). It is also used to synthesize trisubstituted olefins with excellent functional group tolerance and selectivity via cross-metathesis and ring closing metathesis reactions.
It can also be used as a catalyst:
To synthesize coumarins from phenolic compounds via RCM.
To cleave secondary (E)-allyl vic-diols to aldehydes.

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
Learn more about ChemBeads products

For larger scale uses, product is also available in powdered form (569747)

Other Notes

569755 Hoveyda-Grubbs Catalyst 2nd Generation

Grubbs Catalyst Technology for Olefin Metathesis by Aldrich

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

Legal Information

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

Molecular Weight: 848.97. Empirical Formula: C₄₆H₆₅Cl₂N₂PRu. form: solid. Quality Level: 100. composition: ~ 4 wt.% loading of catalyst . reaction suitability: reagent type: catalyst
core: ruthenium
reaction type: Ring-Opening Polymerization. storage temp.: 2-8°C. SMILES string: CC1: CC(C): CC(C): C1N(CCN2C3: C(C: C(C: C3C)C)C)[C-2]2: [Ru+6](P(C4CCCCC4)(C5CCCCC5)C6CCCCC6)([Cl-])([Cl-]): [C-2]C7: CC: CC: C7. InChI: 1S/C21H26N2.C18H33P.C7H6.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6. 1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18. 1-7-5-3-2-4-6-7. . . /h9-12H,7-8H2,1-6H3. 16-18H,1-15H2. 1-6H. 2*1H. /q. . . . . +2/p-2. InChI key: FCDPQMAOJARMTG-UHFFFAOYSA-L. Pictograms: GHS02,GHS08. Signal Word: Danger. Hazard Statements: H228 - H350i. Precautionary Statements: P202 - P210 - P240 - P241 - P280 - P308 + P313. Hazard Classifications: Carc. 1B Inhalation - Flam. Sol. 2. Storage Class Code: 4.1B - Flammable solid hazardous materials. WGK: WGK 3. Flash Point(F): Not applicable. Flash Point(C): Not applicable.