DIMETHYLZINC 2.0M SOLUTION IN TOLUENE (C005B-047967)

Application

Dimethylzinc can be used as:

• A catalyst with nickel for the stereoselective C−2 alkenylation and dialkenylation of pyridine derivatives by alkynes to give monoalkenylation products.
• A reagent with aldehydes and 2-methoxyaniline for the enantioselective synthesis of alkyl and aralkyl secondary amines via one-pot three-component coupling reaction in the presence of zirconium tetraisopropoxide.
• A methylating reagent for the methylation of fluoroalkylated pyruvates in the presence of a copper/chiral diphosphine catalyst.
• An activator for radical trifluoromethylation of silyl enol ethers leading to α-trifluoromethyl ketones.

Molecular Weight: 95.46. Empirical Formula: C₂H₆Zn. linearFormula: (CH₃)₂Zn. Quality Level: 100. concentration: 2.0 . M in toluene. density: 0.931 . g/mL . at 25 . °C. SMILES string: C[Zn]C. InChI: 1S/2CH3.Zn/h2*1H3. . InChI key: AXAZMDOAUQTMOW-UHFFFAOYSA-N. Pictograms: GHS02,GHS05,GHS07,GHS08,GHS09. Signal Word: Danger. Hazard Statements: H225 - H250 - H260 - H304 - H314 - H336 - H361d - H373 - H410. Precautionary Statements: P210 - P231 + P232 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P370 + P378. Hazard Classifications: Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 1. Target Organs: Central nervous system. Storage Class Code: 4.2 - Pyrophoric and self-heating hazardous materials. WGK: WGK 3. Flash Point(F): 1.4 °F - closed cup. Flash Point(C): -17 °C - closed cup. Personal Protective Equipment: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter.