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dimethyl malonate (c15-1203-048)

DIMETHYL MALONATE 98% (C005B-006918)

Catalog No.
C005B-006918
Manufacturer No.
136441-1KG
Manufacturer Name
Sigma-Aldrich
Quantity
1
Unit of Measure
KG

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Dimethyl malonate undergoes enantioselective palladium-catalyzed allylic substitution reaction with 1,3-diphenylprop-2-enyl acetate to yield diastereomeric pure thienylpyridines . Application Dimethyl malonate was used in gold catalyzed oxidative

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General description

Dimethyl malonate undergoes enantioselective palladium-catalyzed allylic substitution reaction with 1,3-diphenylprop-2-enyl acetate to yield diastereomeric pure thienylpyridines.

Application

Dimethyl malonate was used in gold catalyzed oxidative esterification of glycerol, 1,2-propanediol and 1,3-propanediol.

Molecular Weight: 132.11. Empirical Formula: C5H8O4. linearFormula: CH2(COOCH3)2. vapor density: >. 1 (vs air). Quality Level: 200. Assay: 98%. form: liquid. refractive index: n20/D 1.413 (lit.). bp: 180-181 . °C (lit.). mp: −. 62 . °C (lit.). solubility: alcohol: miscible, diethyl ether: miscible, oil: miscible, water: slightly soluble. density: 1.156 . g/mL . at 25 . °C (lit.). SMILES string: COC(: O)CC(: O)OC. InChI: 1S/C5H8O4/c1-8-4(6)3-5(7)9-2/h3H2,1-2H3. InChI key: BEPAFCGSDWSTEL-UHFFFAOYSA-N. Pictograms: GHS07. Signal Word: Warning. Hazard Statements: H319. Precautionary Statements: P264 - P280 - P305 + P351 + P338 - P337 + P313. Hazard Classifications: Eye Irrit. 2. Storage Class Code: 10 - Combustible liquids. WGK: WGK 1. Flash Point(F): 185.0 °F - closed cup. Flash Point(C): 85 °C - closed cup. Personal Protective Equipment: Eyeshields, Gloves, type ABEK (EN14387) respirator filter.
UPC:
12352105
Condition:
New
HazmatClass:
Yes
MPN:
136441-1KG
CAS:
108-59-8

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