DIETHYLZINC 1.0M SOLUTION IN HEXANES (C005B-048647)

Application

Diethylzinc solution can be used as a reagent to prepare:

• α-trifluoromethyl ketones from α, β-unsaturated ketones with Rh (I) catalyst.
• Alkynylzinc reagents which are used in cross-coupling reactions.
• Chiral secondary alcohols from aromatic and aliphatic aldehydes in presence of camphor-derived β-amino alcohol.
• 1, 4 conjugate addition product with enones.
• α-fluoroacrylates from aldehydes and ketones.

Molecular Weight: 123.51. Empirical Formula: C₄H₁₀Zn. linearFormula: (C₂H₅)₂Zn. Quality Level: 100. concentration: 1.0 . M in hexanes. density: 0.726 . g/mL . at 25 . °C. SMILES string: CC[Zn]CC. InChI: 1S/2C2H5.Zn/c2*1-2. /h2*1H2,2H3. . InChI key: HQWPLXHWEZZGKY-UHFFFAOYSA-N. Pictograms: GHS02,GHS05,GHS07,GHS08,GHS09. Signal Word: Danger. Hazard Statements: H225 - H250 - H260 - H304 - H314 - H336 - H361f - H373 - H411. Precautionary Statements: P210 - P231 + P232 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P370 + P378. Hazard Classifications: Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 Inhalation - STOT SE 3 - Water-react 1. Target Organs: Central nervous system, Nervous system. Supp Hazards: EUH014. Storage Class Code: 4.2 - Pyrophoric and self-heating hazardous materials. WGK: WGK 3. Flash Point(F): -9.4 °F - closed cup. Flash Point(C): -23 °C - closed cup. Personal Protective Equipment: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter.