DICHLOROPHENYLBORANE 97% (C005B-083416)

Application

Catalyst for:

• Antiproliferative macrolide and cell migration inhibitor lactimidomycin
• Enantioselective synthesis of polyketide segments using vinylogous Mukaiyama aldol reactions
• Enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives
• Stereoselective alkylative ring opening of cyclic anhydrides
• Cross-metathesis reaction of amino derivatives with olefins
• Asymmetric acetate aldol reactions
• The reaction of aryl aldehydes with styrene and (E)-β-methylstyrene

Dichlorophenylborane can be used as a catalyst for:

• The synthesis of an antiproliferative macrolide and cell migration inhibitor lactimidomycin.
• Enantioselective synthesis of polyketide segments using vinylogous Mukaiyama aldol reactions.
• Enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives.
• Stereoselective alkylative ring opening of cyclic anhydrides.
• Cross-metathesis reaction of amino derivatives with olefins.
• Asymmetric acetate aldol reactions.

Molecular Weight: 158.82. Empirical Formula: C₆H₅BCl₂. Quality Level: 100. Assay: 97%. reaction suitability: reagent type: reductant. refractive index: n20/D 1.545 (lit.). bp: 66 . °C/11 . mmHg (lit.). density: 1.224 . g/mL . at 25 . °C (lit.). SMILES string: ClB(Cl)c1ccccc1. InChI: 1S/C6H5BCl2/c8-7(9)6-4-2-1-3-5-6/h1-5H. InChI key: NCQDQONETMHUMY-UHFFFAOYSA-N. Pictograms: GHS02,GHS05. Signal Word: Danger. Hazard Statements: H225 - H314. Precautionary Statements: P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338. Hazard Classifications: Flam. Liq. 2 - Skin Corr. 1B. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Personal Protective Equipment: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter.