General description
Cyclohexanone diethyl ketal (1,1-Diethoxycyclohexane) reacts with 1,3,2-benzodioxaborole [catecholborane (CB)] to form the corresponding ether. It undergoes thermal elimination reaction in gas-phase to yield 1-ethoxycyclohexene and ethanol.
Application
Cyclohexanone diethyl ketal may be used in the preparation of 1-ethoxycyclohexene.
Molecular Weight: 172.26. Empirical Formula: C
10H
20O
2. Quality Level: 100. Assay: 97%. refractive index:
n20/D 1.4360 (lit.). bp: 76-78 . °C/20 . mmHg (lit.). density: 0.908 . g/mL . at 25 . °C (lit.). SMILES string: CCOC1(CCCCC1)OCC. InChI: 1S/C10H20O2/c1-3-11-10(12-4-2)8-6-5-7-9-10/h3-9H2,1-2H3. InChI key: MWUDABUKTZAZCX-UHFFFAOYSA-N. Pictograms: GHS02,GHS07. Signal Word: Warning. Hazard Statements: H226 - H315 - H319 - H335. Precautionary Statements: P210 - P302 + P352 - P305 + P351 + P338. Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3. Target Organs: Respiratory system. Storage Class Code: 3 - Flammable liquids. WGK: WGK 2. Flash Point(F): 140.0 °F. Flash Point(C): 60 °C. Personal Protective Equipment: Eyeshields, Gloves, type ABEK (EN14387) respirator filter.