Application
Copper(I) iodide can be used as a catalyst for:
- For arylation of pyrazole and derivatives by coupling arenediazonium species under mild and ligand-free conditions.
- Selective cross-coupling of dibromo alkenes and heteronucleophiles which leads to numerous building blocks such as 1-bromoenamides, ynamides, ketene N, N-acetals, 1-bromoenol ethers, ynol ethers, ketene O, O-acetals, and vinyl phosphonates.
- Stereospecific and the regioselective reaction of silacyclopropanes with carbonyl compounds.
It can also be used as a starting material in the preparation of diphenylphosphinepyridine-derivatives (PyrPHOS)-copper iodide complexes which are suitable for use in OLEDs.
Features and Benefits
- Low toxicity
- Mild reaction condition
- High purity ensures reproducibility and avoids cocatalysis by contaminants.
Molecular Weight: 190.45. Empirical Formula: CuI. vapor pressure: 10 mmHg ( 656 °C). Quality Level: 200. Assay: 99.999% trace metals basis. form: powder and chunks. impurities: ≤. 15.0 . ppm Trace Metal Analysis. bp: 1290 . °C/1 . atm (decomp)(lit.). mp: 605 . °C (lit.). solubility: dilute aqueous acid: insoluble(lit.). density: 5.62 . g/mL . at 25 . °C (lit.). application(s): battery manufacturing. SMILES string: [Cu+].[I-]. InChI: 1S/Cu.HI/h. 1H/q+1. /p-1. InChI key: LSXDOTMGLUJQCM-UHFFFAOYSA-M. Pictograms: GHS05,GHS07,GHS08,GHS09. Signal Word: Danger. Hazard Statements: H302 - H315 - H317 - H318 - H372 - H410. Precautionary Statements: P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P314. Hazard Classifications: Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT RE 1 Oral. Target Organs: Thyroid. Storage Class Code: 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects. WGK: WGK 3. Flash Point(F): Not applicable. Flash Point(C): Not applicable. Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves.