Borane dimethyl sulfide complex (C007B-068749)

General DescriptionBorane dimethyl sulfide complex (BMS) is a commonly used reagent and a mediator for hydroboration reaction for the preparation of organoborane compounds, which are utilized as key intermediates in organic synthesis. BMS is also employed as a reducing agent for the reduction of various functional groups such as aldehydes, ketones, epoxides, esters, and carboxylic acids to corresponding alcohols.ApplicationBorane-dimethyl sulfide (BH 3 Me 2 S) can be used as a reagent: For the selective synthesis of 1,3,5-oxygenated compounds from dimethyl 3-oxoglutarate. For the conversion of ozonides to alcohols. In the CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. For enantioselective reduction of ketones to chiral secondary alcohols in the presence of C 3 -symmetric tripodal hydroxyamide as a ligand. For the hydroboration reduction and other applications. With a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.Other Notes10.0-10.2 M as BH 3 . May contain excess methyl sulfide.

Specifications and Purity: 9.8M in Dimethylthioamidine

Molecular Formula: C2H6S·BH3

Molecular Weight: 75.97

EC Number: 236-313-6

PubChem CID: 9833925

Isomeric SMILES: [B].CSC

Beilstein Registry Number: 3663489

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